In this work, the response of the CR-39 nuclear track detector (NTD) exposed to different low doses of gamma rays was investigated using UV–Vis and photoluminescence spectroscopy. Five NTDs of CR-39 were irradiated with low gamma-ray doses ranging from 10 to 120 kGy using a60Co source. The dose of gamma rays correlates with red shift in the absorption spectra of a gamma-irradiated CR-39 detector. As the gamma dose increases, the indirect and direct energy band gaps, as well as Urbach energy, decrease gradually. However, the decrease in the indirect optical band gap is greater than the decrease in the direct band gap. The observed spectra of the CR-39 detector after being irradiated with different doses of γ-rays showed an acceptable variation in photoluminescence (PL) emission spectra generated by a well-defined excitation wavelength of 290 nm. Starting at 45 kGy dose, the integrated area of the photoluminescence peak increases and tends to saturate, whereas the photoluminescence peak height is linearly correlated with the gamma dose with high sensitivity, which is 53.1 ± 6.3 CPS. kGy−1. According to the current findings, photoluminescence (PL) spectroscopy has a greater sensitivity than UV–Vis spectroscopy for measuring the response of the CR-39 detector to gamma rays in the dose range of 10–120 kGy. The results reflected a potential possibility of using the CR-39 detector in dosimetric applications of low gamma ray doses through the high resolution achieved by photoluminescence (PL) and UV–Vis spectroscopy.