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Taguchi Optimization Reveals pH as the Dominant Factor (85% Contribution) in Steel Oxide Film Growth
Faculty
Science
Year:
2026
Type of Publication:
ZU Hosted
Pages:
1-14
Authors:
Ahmed Diab Abdelghafar Khater
Staff Zu Site
Abstract In Staff Site
Journal:
ChemistrySelect Wiley (John Wiley & Sons)
Volume:
vol 11
Keywords :
Taguchi Optimization Reveals pH as the Dominant Factor (85% Contribution) in Steel Oxide Film Growth
Abstract:
This study systematically optimizes the galvanostatic formation of protective steel oxide films, a key process for enhancing corrosion resistance. Employing a Taguchi L1 6 orthogonal array, we evaluated four critical parameters: boric acid concentration (0.001–0.1 M), applied current density (25–100 µA/cm 2 ), temperature (288–318 K), and solution pH (6.11–11.02) using oxide growth rate (dE/dt) as the kinetic response. Analysis of Variance (ANOVA) identified solution pH as the overwhelmingly dominant factor, responsible for 84.96% of the observed variation in film growth rate (dE/dt) underscoring its overwhelming control. A strong positive linear correlation was established, where each unit increase in pH accelerated the growth rate by 0.0248 mV/min. Consequently, the highest growth rates (0.285–0.3125 mV/min) were consistently achieved under alkaline conditions (pH 9.92– 11.02). In contrast, boric acid concentration and current density had minor effects, and temperature was statistically insignificant. The resulting linear model, dE/dt = 0.0355 + 0.0248 pH, robustly confirms pH as the primary predictive variable. The integrated Taguchi-ANOVA-regression approach reduced experimental runs by 93.75% compared to a full factorial design, providing an efficient framework for industrial coating processes where precise pH management is paramount.
Author Related Publications
Ahmed Diab Abdelghafar Khater, "Electrochemical behavior of steel in citric acid solutions devoid of and containing some organic compounds", IJTMER, 2015
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Ahmed Diab Abdelghafar Khater, "Formation of a Passive Oxide Film on Indium Electrode in Aqueous Solutions", IJSER, 2016
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Ahmed Diab Abdelghafar Khater, "Some factors affecting on the behavior of steel electrode in citric acid solutions", IJERA, 2015
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Ahmed Diab Abdelghafar Khater, "Aniline and some of its derivatives as corrosion inhibitors for nickel in 1M HCl solution", society of chemistry, 1999
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Ahmed Diab Abdelghafar Khater, "Anodic Dissolution of Nickel in Acidic Chloride Solutions", ASM International, 2002
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Department Related Publications
Mohamed Gamal Helmy Mohamed Abdelwahed, "Electronic Properties of Organic Complexes. 2. Reactive Azodyes", Spain, 1993
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Mohamed Gamal Helmy Mohamed Abdelwahed, "Electrical Behaviour of some Azodye Mixed Ligand with Gd3+ and Er3+. b", Peru, 1994
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Atef Mohamed AbdelHamid Ali Hassn, "heterocyclization of thiouracil derivative: synthesis of thiazolopyrimidines, tetrazolopyrimidines and triazolopyrimidines of potential biological activity", elsevier, 2015
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Ahmed Abdelmoniem Ahmed Amer, "Synthesis and characterization of some calcium aluminate phases from nano-size starting materials", 0366-3175/© 2020 SECV. Published by Elsevier Espana, ˜ S.L.U, 2020
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