The conducted research offers an environmental assessment of municipal waste (MW) using remote sensing (RS), geological, and geophysical datasets. As a test site, the present study aims to characterize one of the largest uncontrolled dumpsites in Egypt. RS data analysis indicates that high temperature values are concentrated at the MW and landfill site allocations as a result of the decomposition process, leading to fire risks. Moreover, the geological and structural data draw attention to the structural-controlled old topography role on MW distributions. Consequently, the dumpsite MW has larger surface quantities near the downthrows of the mapped faults. For MW characterization, geophysical data are acquired to produce 2D/3D resistivity models. Because MW has the ability to become soft clay, the municipal organic waste and landfill leachate resistivities are lower than that of municipal solid waste and sandy soils. The geophysical inversion results indicate that the maximum thickness of MW calibrating with the drilled borehole data is 60 m. Furthermore, the estimated MW dumpsite volume is about 42.32 MCM. Accordingly, the MW can be characterized in an accurate qualitative and quantitative manner. Our findings, therefore, help the efforts of uncontrolled dumpsite development and thus contribute to sustainability plans.