Enhancement of methylene blue catalytic reduction by novel green synthesized metal decorated reduced graphene oxide: Sn@rGO and Ag@rGO

Faculty Engineering Year: 2024
Type of Publication: ZU Hosted Pages:
Authors:
Journal: Journal of Alloys and Compounds elseiver Volume:
Keywords : Enhancement , methylene blue catalytic reduction , novel    
Abstract:
Carbon-based nanocomposites (NCs) attracted much attention in heterogeneous catalysis to remove organic dyes. Herein, a novel low-cost green approach was utilized to design a reduced graphene oxide (rGO) impregnated with Sn or Ag nanoparticles (NPs) using ginger extract as a green reducing agent. The synthesized NCs were characterized utilizing X-ray diffraction (XRD), Fourier transformation infrared (FTIR), transmission electron microscopy (TEM), energy-dispersive X-ray (EDX), Raman spectroscopy, and thermal gravimetric analysis (TGA). The synthesized NCs were assessed for their catalytic reduction activity towards methylene blue (MB) dye. XRD displayed the characteristic peaks of Sn- and Ag-NPs and the reduction of GO, referring to successful NC formation. FTIR and Raman confirmed the reduction of GO and the incorporation of Sn and Ag-NPs into the GO surfaces. TEM results proved that either Sn- or Ag-NPs was uniformly dispersed on rGO sheets with average sizes of 4.129 and 7.293 nm, respectively. EDX spectra of Sn@rGO- and Ag@rGO-NCs revealed the presence of C, O, Sn, and Ag. TGA confirmed the increased thermal stability of the NCs as compared to GO. Ag@rGO-NC exhibited stronger catalytic MB reduction (97% after 10 min) than Sn@rGO-NC (80% after 20 min). To the best of our knowledge, this is the first time Sn@rGO-NC has been designed for MB catalytic reduction, which gives rise to its promising capacity for future catalytic applications.
   
     
 
       

Author Related Publications

  • Walaa AbdelAzim Abdulaziz AbdelAal, "Microstructure evolution and mechanical properties of Al/Al–12%Si (multilayer processed by accumulative roll bonding (ARB", ScienceDirect, 2015 More
  • Walaa AbdelAzim Abdulaziz AbdelAal, "Effect of surface roughness due to wire brushing on cold roll bonding of Al 1050 sheets", كلية الهندسة, 2015 More
  • Walaa AbdelAzim Abdulaziz AbdelAal, "Grain size affecting the deformation characteristics via micro-injection upsetting", springer, 2021 More
  • Walaa AbdelAzim Abdulaziz AbdelAal, "Synthesis and Characterization of Hybrid Fiber-Reinforced Polymer by Adding Ceramic Nanoparticles for Aeronautical Structural Applications", MDPI, 2021 More
  • Walaa AbdelAzim Abdulaziz AbdelAal, "Metallurgical analysis of ASME SA213 T12 boiler vertical water-wall tubes failure", elsevier, 2023 More

Department Related Publications

  • Soliman Soliman Soliman Alieldien, "A first-order shear deformation finite element model for elastostatic analysis of laminated composite plates and the equivalent functionally graded plates", Ain Shams Engineering Journal, 2011 More
  • Soliman Soliman Soliman Alieldien, "Size-dependent analysis of functionally graded ultra-thin films", Structural Engineering and Mechanics, Vol. 44, No. 4 (2012) 431-448, 2012 More
  • Soliman Soliman Soliman Alieldien, "Bending Analysis of Ultra-thin Functionally Graded Mindlin Plates Incorporating Surface Energy Effects", International Journal of Mechanical Sciences, 2013 More
  • Soliman Soliman Soliman Alieldien, "Finite element analysis of functionally graded nano-scale films", Finite Elements in Analysis and Design, 2013 More
  • Soliman Soliman Soliman Alieldien, "Finite Element Analysis of the Deformation of Functionally Graded Plates under Thermomechanical Loads", Mathematical Problems in Engineering, 2013 More
Tweet