Adsorption and Kinetics Modelling for Chromium (Cr6+) Uptake from Contaminated Water by Quaternized Date Palm Waste

Faculty Engineering Year: 2024
Type of Publication: ZU Hosted Pages:
Authors:
Journal: Water MDPI Volume: 16
Keywords : Adsorption , Kinetics Modelling , Chromium (Cr6+) Uptake    
Abstract:
The pervasive challenge of heavy metal pollution in water necessitates urgent interventions to mitigate chromium contamination. It poses significant threats to human health, aquatic ecosystems, and the environment. This research delves into the potential of date palm waste as a precursor of adsorbent for extraction of chromium from contaminated water, underscoring its potential in heavy metal remediation. Date palm waste, traditionally regarded as agricultural waste, underwent modification employing N-(3-chloro-2-hydroxypropyl) trimethylammonium chloride resulting in quaternized date palm waste (QDPW) as a prospective adsorbent for chromium extraction. The characterization techniques, including FTIR, SEM/EDX, BET, XRD, TGA/DTA, and element analysis, were employed to examine the structural and surface properties of both DPW and QDPW fibers. Optimal chromium uptake was achieved at a solution pH 6.5 over two hours, with a peak removal efficiency of 88% and an adsorption capacity of 22.26 mg/g. The equilibrium isotherms studies are consistent with Langmuir, Redlich-Peterson, and Sips isotherms, presenting a coefficient of determination (R2) of 0.989, 0.981, and 0.983, respectively. Moreover, the pseudo-second-order model was mostly aligned with the kinetics data with R2 value of 0.999. These findings showed that the quaternized date palm waste can be considered a good option to recycle the date palm waste and reduce the environmental threats in aqueous solution.
   
     
 
       

Author Related Publications

  • Mahmoud Mohamed Mohamed Abdeldaiem, "An initial study about the effect of activated carbon nano-sheets from residual biomass of olive trees pellets on the properties of alkali-activated slag pastes", Elsevier, 2021 More
  • Mahmoud Mohamed Mohamed Abdeldaiem, "Prediction of biogas production from anaerobic Co-digestion of Waste Activated sludge and wheat straw using two-dimensional mathematical models and an artificial neural network", Elsevier, 2021 More
  • Mahmoud Mohamed Mohamed Abdeldaiem, "Sustainable waste management of medical waste in African developing countries: A narrative review", SAGE, 2021 More
  • Mahmoud Mohamed Mohamed Abdeldaiem, "RICE STRAW CHARACTERISTICS AND ITS POTENTIAL ENERGY IN VALENCIA (SPAIN)", IRED, 2019 More
  • Mahmoud Mohamed Mohamed Abdeldaiem, "Modeling and optimization of semi-continuous anaerobic co-digestion of activated sludge and wheat straw using Nonlinear Autoregressive Exogenous neural network and seagull algorithm", Elsevier, 2021 More

Department Related Publications

  • Mahmoud Mohamed Mohamed Abdeldaiem, "Adsorption/bioadsorption of phthalic acid, an organic micropollutant present in landfill leachates, on activated carbons", www.elsevier.com, 2011 More
  • Mahmoud Mohamed Mohamed Abdeldaiem, "Comparative study of the photodegradation of bisphenol A by HO , SO4 − and CO3 −/HCO3 radicals in aqueous phase", Elsevier, 2013 More
  • Amro Abdelaziz Abdelrahman albazz, "Effect of Pressure, Water Depth and Water Flow Rate on Oxygen Saturation Level in Activated Sludge Process", Science Publications, 2011 More
  • Amro Abdelaziz Abdelrahman albazz, "INCREASE OF SELF-PURIFICATION EFFICIENCY OF WATER STREAMS USING ROTATING BIOLOGICAL CONTACTORS (RBC)", The Egyptian Int. J. of Eng. Sci. And Technology, 2009 More
  • Noha Saied Alhady , "reduction of ash sintering precursor components in rice straw by water washing", international journal, 2014 More
Tweet