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ELECTRICAL CONDUCTIVITY AND DIELECTRIC RELAXATION STUDY OF POLYVINYL ACETATE/POLY METHYL METHACRYLATE BLENDS
Faculty
Science
Year:
2012
Type of Publication:
Article
Pages:
Authors:
Ahmed, R. M
DOI:
10.1142/S0217979212501597
Journal:
INTERNATIONAL JOURNAL OF MODERN PHYSICS B WORLD SCIENTIFIC PUBL CO PTE LTD
Volume:
26
Research Area:
Physics
ISSN
ISI:000309384800015
Keywords :
Conductivity, glass transition temperature, polymer blends, polymer films
Abstract:
Transparent films of PMMA (poly methyl methacrylate), PVAc (polyvinyl acetate) and their blends, have been prepared by using a solution-casting technique. The dielectric properties and the electrical conductivity are reported. The frequency and temperature dependence of the dielectric constant, epsilon' and tan delta, have been investigated for the studied samples in the frequency range from 1 kHz to 5 MHz and over a range of temperature from 303-413 K. In addition, AC conductivity values were calculated from the dielectric data and the conduction mechanism is discussed. The frequency-dependent conductivity behavior at different temperatures provides a qualitative description of the conduction mechanism. Also, differential scanning calorimetry (DSC) scans have been measured for the studied samples.
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