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Spectroscopic studies of the reactions of pi-electron acceptors with the cyclic polyamine 1,4,8,11-tetraazacyclotetradecane
Faculty
Science
Year:
1997
Type of Publication:
Article
Pages:
1109-1123
Authors:
NOUR, EM, Metwally, SM, Elmosallamy, MAF, Gameel, Y
DOI:
10.1080/00387019708006710
Journal:
SPECTROSCOPY LETTERS MARCEL DEKKER INC
Volume:
30
Research Area:
Spectroscopy
ISSN
ISI:A1997XT10900011
Keywords :
Spectroscopic studies , , reactions , pi-electron acceptors with
Abstract:
The reactions of pi-electron accepters such as 1-chloro-2,4,6-trinitrobenzene (picryl chloride), 7,7',8,8'-tetracyanoquinodimethane (TCNQ), tetrachloro-p-benzoquinone (chloranil) and tetracyanoethylene (TCNE) with the cyclic polyamine base 1,4,8,11-tetraazacyclotetradecane (TACTD) have been investigated in CHCl3 solvent. The data indicate the formation of the CT-complexes with the general formula {[}(TACTD) (acceptor)(2)]. The 1 : 2 stoichiometry of the (TACTD)-acceptor was based on elemental analysis and infrared spectra of the solid CT-complexes along with the photometric titration curves for the reactions in CHCl3. The formation constants (K) for the CT-complexes are shown to be strongly dependent on the type and structure of the pi-acceptor.
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