Journal: |
Journal of Alloys and Compounds
ElSevier
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Volume: |
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Abstract: |
Cation distribution, structure analysis, elastic moduli, magnetic and dielectric features obtained by the
citrate combustion technique of Co
0.8
Zn
0.2
Cr
x
Fe
2-x
O
(x ¼ 0, 0.02, 0.04, 0.06, 0.08 and 0.1) (CZC) nanoferrites
were investigated. The most intense (311) peak is found to gradually shift towards higher
diffraction angles, and so the lattice constant is found to decrease (from 8.3893 to 8.3698 Å, experimentally)
and (from 8.3893 to 8.3853 Å, theoretically), as the Cr
4
3þ
content increase. The crystallite size of
CZC nanoferrites initially increases from 38 to 42 nm for Cr
3þ
content (x ¼ 0.0 to x ¼ 0.06), and then
decrease from x ¼ 0.08 onwards. Morphological contemplation (FE-SEM, HRTEM) manifests that the
porosity diminishes significantly with increasing Cr
3þ
content meanwhile the particles have some
agglomeration. The elastic moduli and Poisson's ratio of CZC ferrite samples were determined, theoretically
and experimentally, and then corrected to zero porosity using Hosselman and Fulrath's model.
An analogous behavior for experimental and theoretical magnetic moment is obtained, attached with an
increment attitude of YafeteKittel angle on the B-sublattice, which increase (from 39
)as
the Cr
3þ
content increase. The value of impedance is increased (from 44 k U to 203 k U) with increasing
Cr
3þ
content. Nyquist plot shows a single semicircle declaring that the predominant conduction is
through the grain boundary volume. These results behold that substitution with Cr ions and porosity has
prominent impacts on the various properties of Co-Zn nanoferrites, making it nominee for multilateral
applications. The loss of Co
0.8
Zn
0.2
Cr
0.1
Fe
1.9
O
nanoferrite (x ¼ 0.1) is decreased ~ 4 times with increasing
relaxation time from 0.53 to 15.9
ms, which has good predictions for next generation cores of RF
transformers.
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