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Correlating bulk modulus and Poisson's ratio of alkali fluoride and oxyfluoride glasses with compositional parameters
Faculty
Science
Year:
2019
Type of Publication:
ZU Hosted
Pages:
48–55
Authors:
Amin Abdelmoneim Sayed Ahmed eibrhim
Staff Zu Site
Abstract In Staff Site
Journal:
Journal of Fluorine Chemistry ELSEVIER
Volume:
0022-1139
Keywords :
Correlating bulk modulus , Poisson's ratio , alkali
Abstract:
The bulk modulus and Poisson's ratio of the alkali fluoride ZrF4-BaF2-AlF3-LiF-NaF, oxyfluoride borate PbF2- PbO-B2O3 and oxyfluoride tellurite AlF3-ZnO-TeO2 glasses have been correlated with the most significant compositional parameters. These compositional parameters are the packing density, mean atomic volume, fractal bond connectivity and molar volume. For the first time, the more recently Abd El-Moneim and Alfifi's semi-empirical formula, which correlates the experimental bulk modulus with the ratio between packing density and mean atomic volume, has been demonstrated for these types glasses. The correlation between bulk modulus and molar volume has also been carried out. The results indicate that the ratio between packing density and mean atomic volume is established as a good factor in understanding and predicting the elastic moduli of alkali fluoride and oxyfluoride glasses. The experimental Poisson's ratios are predictable from both the fractal bond connectivity and packing density. Excellent agreement was achieved between experimental and theoretical Poisson's ratios. The correlation between bulk modulus and molar volume has also been achieved in alkali fluoride and oxyfluoride tellurite glasses.
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Amin Abdelmoneim Sayed Ahmed eibrhim, "A new factor for predicting the acoustical properties of oxide glasses", Society of Glass Technology, 2018
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Amin Abdelmoneim Sayed Ahmed eibrhim, "On the analysis and prediction of elastic properties in alkali Na2O-B2O3-V2O5 glasses under the substitution of V2O5 by Na2O", Society of Glass Technology, 2019
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Amin Abdelmoneim Sayed Ahmed eibrhim, "Prediction of elastic properties in oxide glasses: extension of Abd El-Moneim and Alfifi’s approaches to lithium borovanadate glasses", Society of Glass Technology, 2019
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Amin Abdelmoneim Sayed Ahmed eibrhim, "Elastic moduli and Poisson's ratio prediction in borate-based PbO-B2O3-V2O5 and Li2O-ZnO-B2O3 glass systems", ELSEVIER, 2019
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