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Copper Electropolishing in the Presence of Purine Derivatives
Faculty
Science
Year:
2013
Type of Publication:
Article
Pages:
1512-1520
Authors:
Ahmed, A. M, Abd El-Haleem, S. M, Saleh, M. G. A, Abdel-Rahman, A. A. -H
Journal:
ASIAN JOURNAL OF CHEMISTRY ASIAN JOURNAL OF CHEMISTRY
Volume:
25
Research Area:
Chemistry
ISSN
ISI:000312621400077
Keywords :
Anodic corrosion, Purine derivatives, Adsorption isotherm, Thermodynamic functions
Abstract:
The electropolishing settings for inhibiting the rate of anodic corrosion of copper plates in phosphoric acid were achieved using potentiodynamic studies including different factors such as plate height, phosphoric acid concentration, type and concentration of mines as well as temperature. The results reveal that purifies have strongest inhibitive effect ranging from 9.7 to 80.1 \% that provides good protection to copper surface against corrosion in phosphoric acid solutions. Its adsorption obeys Langmuir, Flory-Huggins and kinetic adsorption isotherm. Thermodynamic functions computed and discussed.
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