Bis(tri-tert-butylphosphine)palladium(0)-catalyzed iodine–fluorine exchange at closo-carboranes.

Faculty Science Year: 2018
Type of Publication: ZU Hosted Pages:
Authors:
Journal: Bioorganic & Medicinal Chemistry Wiley Volume:
Keywords : Bis(tri-tert-butylphosphine)palladium(0)-catalyzed iodine–fluorine exchange , closo-carboranes.    
Abstract:
The bis(tri-tert-butylphosphine)palladium(0) [Pd(tBu3P)2]-catalyzed synthesis of fluorinated closo-carboranes from 3D aromatic iodo-closo-carboranes by nucleophilic halogen exchange using silver(I) fluoride is described. Fluorination of 2-i
   
     
 
       

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