Zagazig University Digital Repository
Home
Thesis & Publications
All Contents
Publications
Thesis
Graduation Projects
Research Area
Research Area Reports
Search by Research Area
Universities Thesis
ACADEMIC Links
ACADEMIC RESEARCH
Zagazig University Authors
Africa Research Statistics
Google Scholar
Research Gate
Researcher ID
CrossRef
Ultrasonic and structural studies on TiO2-doped CaO-Al2O3-B2O3 glasses
Faculty
Science
Year:
2003
Type of Publication:
Article
Pages:
192-201
Authors:
Abd El-Moneim, A, Youssof, IM, Abd El-Daiem, AM
DOI:
10.1002/pssa.200306651
Journal:
PHYSICA STATUS SOLIDI A-APPLIED RESEARCH WILEY-V C H VERLAG GMBH
Volume:
199
Research Area:
Materials Science; Physics
ISSN
ISI:000185723300005
Keywords :
Ultrasonic , structural studies , TiO2-doped CaO-Al2O3-B2O3 glasses
Abstract:
TiO2-doped 30CaO-30Al(2)O(3)-40B(2)O(3) glasses have been prepared by the melt quenching method over a wide range of composition (TiO2 = 5, 10, 15, and 20 mol\%). The longitudinal velocity and attenuation of ultrasonic waves were measured in these glasses at room temperature using the pulse-echo technique. The acoustic impedance and longitudinal modulus were calculated and are discussed quantitatively in terms of the structural parameters, such as packing density, dissociation energy per unit volume, field strength of the modifiers, number of network bonds per unit volume, average cross-link density and the number of two-well systems (loss centers) per unit volume of the glass. The composition dependence of these parameters suggested that Al2O3 associates itself with CaO to form AlO4 tetrahedra and Ti4+ ions are incorporated in the network as TiO6 octahedra. This leads to an increase in the three-dimensional linkage and rigidity of the network. Moreover, the theoretical elastic moduli were calculated for these glasses from the chemical composition and the experimentally determined density using the Makishima and Mackenzie model. Results showed that the model is valid for the studied glasses. (C) 2003 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim.
Online
PDF
جامعة المنصورة
جامعة الاسكندرية
جامعة القاهرة
جامعة سوهاج
جامعة الفيوم
جامعة بنها
جامعة دمياط
جامعة بورسعيد
جامعة حلوان
جامعة السويس
شراقوة
جامعة المنيا
جامعة دمنهور
جامعة المنوفية
جامعة أسوان
جامعة جنوب الوادى
جامعة قناة السويس
جامعة عين شمس
جامعة أسيوط
جامعة كفر الشيخ
جامعة السادات
جامعة طنطا
جامعة بنى سويف