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Surface and Biological Activity of Some Prepared Iminium Surfactants Based on Schiff Bases
Faculty
Science
Year:
2013
Type of Publication:
Article
Pages:
243-250
Authors:
Aiad, Ismail, El-Deeb, Ali, EL-Sukkary, Mohamed M, El-Awady, Moshira Y, Shaban, Samy M
DOI:
10.1007/s11743-012-1402-8
Journal:
JOURNAL OF SURFACTANTS AND DETERGENTS SPRINGER HEIDELBERG
Volume:
16
Research Area:
Chemistry; Engineering
ISSN
ISI:000314973700012
Keywords :
Cationic surfactants, Quaternary iminium salts, Cationic Schiff bases, Surface parameters, Thermodynamic aspects, Biological activity
Abstract:
A series of novel iminium surfactants were prepared through quaternization of different prepared fatty Schiff bases with benzyl chloride. The chemical structures were confirmed using FTIR, H-1-NMR and mass spectroscopy. The surface properties and biological activity of these surfactants were investigated. The surface parameters including critical micelle concentration (CMC), maximum surface excess (I{''}(max)) and minimum surface area (A (min)), Efficiency (PC20) and Effectiveness (pi(CMC)) as well as the free energy of micellization () and adsorption () were calculated. It was found that the prepared compounds have good surface and biological activity.
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