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PVC-Membrane electrodes based on 18-crown-6 and dibenzo-18-crown-6 ethers for determination of silver
Faculty
Science
Year:
2007
Type of Publication:
Article
Pages:
449-456
Authors:
Akl, Magda A, Zareh, Mohsen Mousa, Gohneim, Ahmd Khlil, El-Aziz, Mohmed Hussin Abd
Journal:
TURKISH JOURNAL OF CHEMISTRY SCIENTIFIC TECHNICAL RESEARCH COUNCIL TURKEY-TUBITAK
Volume:
31
Research Area:
Chemistry; Engineering
ISSN
ISI:000250070600007
Keywords :
Ag plus determination, silver electrode, PVC-membrane electrode.
Abstract:
PVC-membrane electrodes for Ag+ based on either 18-crown-6 ( I) or di-benzo-18-crown-6 ether (II) were applied for the first time. The effect of solvent mediator on the electrode performance was discussed. Nernstian slope values were 59 and 58.9 mV/decade for both I and II electrode types, respectively. The linear concentration range was 10(-5)-10(-1) M. The detection limit was 7.9 x 10(-6) M. The working pH ranges were 5-9 or 4-9, depending on the concentration of Ag+ ion. The electrodes showed good selectivity towards most of the common alkali, alkaline earths, and transition metal cations. The electrodes were applied successfully for the determination of silver in photographic wastewater and alloys that are part of railway engines. The recovery range was 96\%-100\%, and the relative standard deviation was ( 0.95-2.7) for n = 4. The obtained results were compared to those of an atomic absorption spectrophotometric method.
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