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Synthesis and characterization of N,N `-bis{[}2-hydroxyethyl]-1,4,6,8-naphthalenediimide with para substituted of phenols based on charge-transfer complexes
Faculty
Science
Year:
2007
Type of Publication:
Article
Pages:
123-133
Authors:
Refat, Moamen S, El-Sayed, Mohamed Y, Killa, Hamada M. A, Grabchev, Ivo
DOI:
10.1016/j.saa.2006.10.055
Journal:
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY PERGAMON-ELSEVIER SCIENCE LTD
Volume:
68
Research Area:
Spectroscopy
ISSN
ISI:000249837200019
Keywords :
NN'-bis{[}2-hydroxyethyl]-1, 4, 6, 8-naphthalenediimide, phenolic acceptors, CT complexes, thermal studies
Abstract:
The interaction of charge-transfer (CT) complexes resulted from the reaction of N,N'-bis{[}2-hydroxyethyl]-1,4,6,8-naphthalenediimide (BHENDI) with some various acceptors like as substituted phenols in para position; 4-aminophenol (4AP), 4-methylphenol (4MP) and 4-nitrophenol (4NP) have been studied in methanol at room temperature. The reaction was studied using electronic (UV-vis), mid infrared, and (1)H NMR spectra and thermal measurements (TGA and DTG) as well as elemental analysis CHN. The chemical analysis data of the resulted CT-complexes, BHENDI-acceptors, reveal that the formation of a 1:2 CT complexes in all cases. The interaction of N,N'-bis{[}2-hydroxyethyl]- 1,4,6,8-naphthalenediimide and phenolic acceptors were investigated spectrophotometrically and found two detected CT bands have n-pi{*} transition. The donor site involved in CT interaction is the diimide two nitrogen atoms by forming hydrogen bonding. The kinetic thermodynamic parameters like Delta E, Delta H, AS and Delta G are calculated from the DTG diagrams using Coats-Redfem method. The electrical conductivity properties for the solid CT complexes were measured within the temperature of room 25 degrees C. (c) 2006 Elsevier B.V. All rights reserved.
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