Limits determination of toleration of aggressive anions by a certain passivator on zinc surface

The open circuit potentials of Zn electrode were followed as a function of time in different concentrations Na2B4O7 solutions until steady-state, values were attained. The potential shifts immediately towards positive values, indicating film thickening and repair. The effect of addition of NaCl, NaBr and Nal as aggressive agent on the steady-state potential of a Zn electrode previously equilibrated in a passivating borate solution was also established. For each Na2B4O7 concentration, the variation in the potential with the quantity of aggressive anions follows an S-shaped relationship. The new potentials are established after an induction period which decreases with the increase in the concentration of the aggressive anion, C-agg., and/or decreases in that of the passivator anion, C-pass.. The concentration, C-agg., that can be tolerated by a certain concentration of the passivator anion, C-pass., is given by the relation: log C-pass. = k + nlog C-agg., where k and n are constants. This is derived on the basis of competitive adsorption of both types of anion and the structure of the double layer at the metal/solution interface. The implications of the equations are briefly discussed. (c) 2007 Elsevier Ltd. All rights reserved.