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Lamellar molybdenum oxide as a molecular sieve towards nitrogen containing molecules: intercalation compounds with pyridazine, acrylamid and tris(hydroxymethyl)aminomethane
Faculty
Science
Year:
2008
Type of Publication:
Article
Pages:
113-118
Authors:
Refat, Moamen S, de Farias, Robson F, Hashem, Hassan A
DOI:
10.1007/s10847-007-9402-4
Journal:
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY SPRINGER
Volume:
61
Research Area:
Chemistry
ISSN
ISI:000255862700014
Keywords :
molybdenum oxide, intercalation, molecular sieve, amides
Abstract:
The synthesis and characterization (by CHN elemental analysis, FTIR spectroscopy, XRD diffractometry, thermogravimetry and SEM microscopy) of MoO(3) intercalation compounds with pyridazine (pdz), acrylamid (ald) and tris(hydroxymethyl)aminomethane (tham) is reported. Such investigation was performed taking into account the possible uses of molybdenum trioxide as a molecular sieve towards nitrogen containing compounds. It is verified that the affinity of MoO(3) towards the investigated species follows the sequence: ald congruent to > pdz.
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