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The Preparation and Characterization of Some Novel Quaternary Iminium Salts Based on Schiff-base as a Corrosion Inhibitor
Faculty
Science
Year:
2010
Type of Publication:
Article
Pages:
1158-1169
Authors:
Aiad, I, DEEB, A, El-Sukkary, M. M. A, El-Awady, M. Y, Ahmed, H. M, Shaban, S. M
DOI:
10.1080/10916460902967718
Journal:
PETROLEUM SCIENCE AND TECHNOLOGY TAYLOR \& FRANCIS INC
Volume:
28
Research Area:
Energy \& Fuels; Engineering
ISSN
ISI:000278707800008
Keywords :
cationic surfactants, corrosion inhibitors, quaternary iminium salts, surface parameters
Abstract:
Novel quaternary iminium compounds, namely, N-(4-methoxybenzylidene)-N-benzyldodecyliminium chloride (Ia), N-(4-methoxybenzylidene)-N-benzylhexadecyl iminium chloride (Ib), N-(4-methoxybenzylidene)-N-benzyloctadecyliminium chloride (Ic), and N-benzylidene-N-benzyldodecyliminium chloride, were prepared. The surface properties such as surface and interfacial tension, foaming, and emulsifying power of these surfactants were investigated. The surface parameters including critical micelle concentration (CMC), maximum surface excess (max), minimum surface area (Amin), efficiency (PC20), and effectiveness (CMC) were calculated. Free energy of micellization (G degrees mic) and adsorption (G degrees ads) were calculated.
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