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Synthesis and characterizations of charge-transfer complexes of 1.8-naphthalimides with different acceptors
Faculty
Science
Year:
2010
Type of Publication:
Article
Pages:
279-299
Authors:
Refat, M. S, El-Zayat, L, Al Didamony, H, Abou El-Nour, Kh. M, Grabchev, I
Journal:
BULGARIAN CHEMICAL COMMUNICATIONS BULGARIAN ACAD SCIENCE
Volume:
42
Research Area:
Chemistry
ISSN
ISI:000287118100003
Keywords :
Charge-transfer, spectroscopic studies, acceptors, 1.8-naphthalimide
Abstract:
Five new Charge-Transfer (CT) complexes, formed from the of 4-substituted-N-allyl-1.8-naphthalimide derivatives as donors and sigma-acceptor (iodine or pi-acceptors) have been investigated. The data obtained indicate the formation of CT-complexes with the general formula of {[}(donors)(acceptor)(n)], where n= 1 in the case of {[}(donors)]I-2, {[}(donors)(DDQ)], {[}(donors)(CLA)], {[}(donors)(PA)] complexes and {[}(donors)(TCNQ)] except for {[}(4MAN)(TCNQ)(2)], and {[}(4PAN)(TCNQ)(2)] where n = 2.
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