Microwave-Assisted Molybdenum-Catalyzed Reductive Cyclization of o-Nitrobenzylidene Amines to 2-Aryl-2H-indazoles

Faculty Science Year: 2013
Type of Publication: Article Pages: 1573-1577
Authors: DOI: 10.1055/s-0033-1339195
Journal: SYNLETT GEORG THIEME VERLAG KG Volume: 24
Research Area: Chemistry ISSN ISI:000321610300022
Keywords : catalysis, cyclization, indazoles, molybdenum, Schiff bases    
Abstract:
The reductive cyclization of o-nitrobenzylidene amines under microwave conditions employing MoO2Cl2(dmf)(2) as catalyst and Ph3P as reducing agent delivers 2-aryl-2H-indazoles with yields ranging from 61-92\%.
   
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