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Surface Properties, Thermodynamic Aspects and Antimicrobial Activity of Some Novel Iminium Surfactants
Faculty
Science
Year:
2012
Type of Publication:
Article
Pages:
359-366
Authors:
Aiad, Ismail, El-Deeb, Ali, EL-Sukkary, Mohamed M, El-Awady, Moshira Y, Shaban, Samy M
DOI:
10.1007/s11743-011-1317-9
Journal:
JOURNAL OF SURFACTANTS AND DETERGENTS SPRINGER HEIDELBERG
Volume:
15
Research Area:
Chemistry; Engineering
ISSN
ISI:000303064100013
Keywords :
Cationic surfactants, Quaternary ammonium salts, Surface parameters, Thermodynamic aspects and biological activity
Abstract:
Novel iminium compounds namely p-benzylidene benzyldodecyl iminium chloride (I), p-benzylidene benzylhexadecyl iminium chloride (II), p-benzylidene benzyloctadecyl iminium chloride (III) were prepared and characterized using FTIR, H-1-NMR and mass spectroscopy. The surface properties such as surface and interfacial tension, and biological activity of these surfactants were investigated. The surface parameters including critical micelle concentration, maximum surface excess, and minimum surface area. Efficiency and effectiveness were calculated, as well as free energies of micellization and adsorption. The prepared cationic surfactants exhibit a better biological activity than the used reference cetyl trimethyl ammonium bromide.
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