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ELECTROCHEMICAL INVESTIGATION OF TERNARY COMPLEXES OF CD(II) WITH SOME AMINO-ACIDS (ALPHA-ALANINE AND BETA-ALANINE) AND CITRATE ANIONS
Faculty
Not Specified
Year:
1991
Type of Publication:
Article
Pages:
1193-1199
Authors:
KILLA, HM, GHONEIM, MM, MABROUK, ESM
Journal:
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS INST ORGANIC CHEM AND BIOCHEM
Volume:
56
Research Area:
Chemistry
ISSN
ISI:A1991FV20200005
Keywords :
ELECTROCHEMICAL INVESTIGATION , TERNARY COMPLEXES , CD(II) WITH
Abstract:
The ternary complexes of Cd(II) with citrate anions as a primary ligand and amino acids (alpha-alanine and beta-alanine) as a secondary ligand have been investigated using differential pulse polarography. Formation of three mixed complexes, {[}Cd(amino acid)(cite)], {[}Cd(amino acid)(citrate)2] and {[}Cd(amino acid)2(citrate)] is observed in each case. The stability constants and the mixing constants of the ternary system have been calculated, as well as the stabilization constants. The electrochemical reduction was reversible and diffusion controlled. The various equilibria involved in the ternary systems are also given.
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