SYNTHESIS AND REACTIONS OF SOME NEW ORGANOMETALLIC COMPOUNDS - SYNTHESIS OF TRIPHENYLSILYLSULFINYLAMINE

Faculty Science Year: 1992
Type of Publication: Article Pages: 253-255
Authors:
ISMAIL, NA, YASSIN, FA, Ahmed, GA
DOI: 10.1080/10426509208040643
Journal: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS GORDON BREACH SCI PUBL LTD Volume: 69
Research Area: Chemistry ISSN ISI:A1992JP44100006
Keywords : TRIPHENYLSILYLSULFINYLAMINE, TRIPHENYLSILYLAMINE, THIONYLCHLORIDE, N-SULFINYL, SULFODIMIDE, SUFINYL AMINE    
Abstract:
Triphenylsilylsulfinylamine (1) was prepared via the reaction of triphenylsilylamine and thionylchloride. The reaction of (1) with copper and sodium metals gave the corresponding azo, and thioazo-derivatives (2, 3). Also cycloaddition products (4a-c) were prepared through the reaction of (1) with some alkenes under Diels-Alder reaction conditions. The nitrilimine (5) was reacted with (1) to give 1,2,3,5-thiatriazole-1-oxide (6).
    
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